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The Non-Ergodic Nature of Internal Conversion

An Experimental and Theoretical Approach

Thomas Scheby Kuhlman

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Springer International Publishing img Link Publisher

Naturwissenschaften, Medizin, Informatik, Technik / Physikalische Chemie

Beschreibung

This thesis investigates the transitions from one electronically excited state to another. Such processes - the fastest of events in chemistry - can be studied with femtosecond resolution, and Thomas S. Kuhlman approaches the question both with experimental and theoretical methods. His approach contributes to explain processes of high importance to all scientific fields concerned with the interaction between light and matter: the deactivation of the electronically excited states after excitation. Thomas S. Kuhlman concludes in this thesis that the electronic transition proceeds before the entire set of available degrees of freedom are active - 'It is as simple as that' !

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Schlagwörter

Time-resolved Spectrosopy of Gas-phase Molecules, Quantum Dynamics Simulations, Transition between Electronically Excited States, Gas-phase Femtochemistry of Organic Molecules, Femto-second Time-resolved Photoionization, Multi-configuration time-dependent Hartree Calculations, The Born-Oppenheimer Approximation, Cycloketones, Cyclopentadienes and Dithiane, Deactivation of Electronically Excited States, Non-statistical Aspects of Molecular Dynamics