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Electrophosphorescent Polymers Based on Polyarylether Hosts

Shiyang Shao

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Springer Berlin img Link Publisher

Naturwissenschaften, Medizin, Informatik, Technik / Maschinenbau, Fertigungstechnik

Beschreibung

This thesis introduces a series of novel, non-conjugated polyarylether hosts that are not subject to the triplet-energy limitations of traditional conjugated polymer hosts. As a result of this major breakthrough, the long-standing problem of triplet energy back transfer has now been overcome, making it possible to design high-efficiency electrophosphorescent polymers (PhPs), especially the blue and all-phosphorescent white ones. In addition, the author proposes a spiro-linked hyperbranched architecture for PhPs to inhibit the undesired triplet energy back transfer process in low triplet-energy hosts. The work in this thesis provides vital new insights into the design of PhPs and has led to several publications in high-profile journals.

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Schlagwörter

Triplet energy back transfer (TEBT), Blue electrophosphorescent polyarylethers, Spiro-linked hyperbranched architecture, All-phosphorescent white PhPs, Electrophosphorescent polymer (PhPs), Organic Electroluminescence, Non-conjugated polymers, Phosphorescent polymer light emitting diodes (PhPLEDs), Electroluminescent materials, Polyarylether hosts