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Cyclometalation Reactions

Five-Membered Ring Products as Universal Reagents

Iwao Omae

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Springer Tokyo img Link Publisher

Naturwissenschaften, Medizin, Informatik, Technik / Organische Chemie

Beschreibung

This book provides a review of cyclometalation reactions and organometallic intramolecular-coordination five-membered ring products, the most active type of reactions in synthetic organic reactions and their products. Included is the discovery of intramolecular-coordination bonds in cyclometalation reactions and the characteristics of those reactions, as well as the reasons that their five-membered ring compounds are very easily synthesized through such reactions. In addition, the applications of cyclometalation reactions and five-membered ring products, synthetic applications, catalysts, and other products are described. These topics are of special interest for industrial researchers.

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Schlagwörter

C-X Activation, C-H Functionalization, C-H Activation, Coordination Bond, Agostic Interaction, Organometallic Intramolecular-Coordination, Cyclometalation, Chelate Effect, Five-membered Ring